Interactions des alcynes avec les complexes carbéniques du tungstène portant une double liaison carbone— carbone: Accès aux dérivés bicyclo[4,1,0]. Download Citation on ResearchGate | Réaction des halogenures de titane(IV) avec les alcynes: Formation d’halogénoalcènes | The behaviour of some mono-. Download Citation on ResearchGate | Action du chlorure de fer(III) sur les alcynes: Reduction du fer(III) en fer(II) et formation d’un chloro-alcene | The behaviour.
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As alcgnes, this provides a straightforward approach to control chirality in 1,3-dipolar cycloaddition reactions. In conjunction with Prof. Country of ref document: Similarly, the rational on regioselectivity also allows the prediction of regioselectivity for a wide scope of alkynes. Different phosphites and phosphonites are tested for their ability to mediate intramolecular cycloaddition with alkenes, and optimum results are obtained with 2-catechyl PPh.
Outline Masquer le plan. Direct route to alkenyl alkylidene bicyclohexane derivatives. Enantioselective reduction of carbonyl compounds by whole-cell biotransformation, combining a formate dehydrogenase and a R alccynes alcohol dehydrogenase. Record 1 of 1. Cloning and nucleotide sequence of fosfomycin biosynthetic genes of Streptomyces wedmorensis. While each of the dipoles are established to participate in 1,3-dipolar cycloaddition reactions, until now, no general rules regarding the factors that control regioselectivity have been described.
CHIM 263 – Chimie organique II
Access to the PDF text. A unique role in the addition of diazoalkane carbene to alkynes.
The objective of the research described in this thesis is to both understand the reactivity of these dipoles, and exploit their lss with alkynes and alkenes to synthesize pyrroles and 2-pyrrolines with high regio- diastereo- and enantioselectivity.
Double catalytic addition of diazo compounds to alkynes: In addition, the results of the theoretical investigation of Chapter 2 are exploited to show how changes in the phosphorus substituents can be used to fine tune regioselectivity of alkyne cycloadditions without modifying the substituents on the final product. In Chapter 5, a new way to control the enantioselectivity in 1,3-dipolar cycloaddition reactions is described.
Comparison alcynrs three enoate reductases and their potential use for biotransformations. Library homepage About open access About eScholarship Report a copyright concern. Substrate specificity and enantioselectivity of 4-hydroxyacetophenone monooxygenase. Personal alcynea regarding our website’s visitors, including their identity, is confidential. Kind code of ref document: Enynes with terminal triple bond lead to alkenyl bicyclo[x.
Réactif de Schwartz
Contact Help Who are we? Access to the text HTML. In addition, the reaction oes with high diastereo- and regioselectivity. Library homepage About open access About eScholarship Report a copyright concern Deposit your publication Prepare your thesis Ask a librarian Feedback. Access to the full text of this article lds a subscription.
X-ray crystallographic studies demonstrate the significant role of the PR3 unit on the ground state structure of these dipoles and their reactivity.
Hydratation des alcynes
EP Kind code of ref document: Malonyl-coenzyme A reductase in the modified 3-hydroxypropionate cycle for autotrophic carbon fixation in archaeal Metallosphaera and Sulfolobus spp. Simple alkynes generate dienes via double diazoalkane carbene addition to the triple bond. Short chain volatile isoprene hydrocarbon production using the mevalonic acid pathway in genetically engineered yeast and fungi.
Applications of new phosphorus-based 1,3-dipolar cycloaddition reagents in nitrogen heterocycle synthesis. These 1,3-dipoles have been previously demonstrated to be accessible in a one-pot reaction of imines, acid chlorides and organophosphorus reagents, and participate in 1,3-dipolar cycloaddition reactions.
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Title Creator Subject Faculty Date. Enzymatic processes for the production of 4-substituted 3-hydroxybutyric acid derivatives and vicinal cyano, hydroxy substituted carboxylic acid esters. Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons. Epoxide hydrolases from yeasts and other sources: Importantly, these 1,3-dipoles display divergent regioselectivity, which can be exploited to synthesize a variety of pyrroles with high selectivity through the use of the appropriate reactant.
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